| Player | Walks |
|---|---|
| Gaylord Perry | 142 |
| Dazzy Vance | 155 |
| John Smoltz | 159 |
| Stan Coveleski | 160 |
| Don Drysdale | 194 |
| Robin Roberts | 199 |
| Dizzy Dean | 202 |
| Mickey Welch | 206 |
| Carl Hubbell | 208 |
| Jim Bunning | 210 |
| Catfish Hunter | 212 |
| Johan Santana | 215 |
| Greg Maddux | 216 |
| Spud Chandler | 231 |
| Bret Saberhagen | 232 |
| Curt Schilling | 252 |
| Denny McLain | 258 |
| Kid Nichols | 259 |
| Whitey Ford | 262 |
| Cy Young | 266 |
| Juan Marichal | 266 |
| Sid Fernandez | 267 |
| Don Sutton | 269 |
| Pedro Martinez | 273 |
| Addie Joss | 285 |
| Lefty Grove | 290 |
| Dean Chance | 290 |
| Christy Mathewson | 304 |
| Bob Lemon | 308 |
| Mordecai Brown | 309 |