| Player | Season | Walks |
|---|---|---|
| Greg Maddux (VGA) | 3 | 46 |
| Greg Maddux (VGA) | 4 | 46 |
| Bret Saberhagen (VGA) | 3 | 46 |
| Don Drysdale (STL) | 3 | 50 |
| Juan Marichal (STL) | 3 | 53 |
| Carl Hubbell (VGA) | 2 | 54 |
| Don Sutton (NOH) | 1 | 56 |
| Don Sutton (NOH) | 3 | 56 |
| Fergie Jenkins (OTT) | 3 | 59 |
| Robin Roberts (NOH) | 3 | 61 |
| Greg Maddux (VGA) | 1 | 62 |
| Greg Maddux (VGA) | 2 | 62 |
| Juan Marichal (STL) | 4 | 64 |
| Johan Santana (OTT) | 3 | 64 |
| Mordecai Brown (NOH) | 4 | 67 |
| Robin Roberts (NOH) | 4 | 67 |
| Carl Hubbell (STL) | 1 | 69 |
| Addie Joss (STL) | 3 | 69 |
| Addie Joss (STL) | 4 | 69 |
| Carl Mays (SPB) | 1 | 69 |
| Bert Blyleven (GRR) | 2 | 70 |
| Warren Spahn (PTL) | 4 | 70 |
| Cy Young (GRR) | 3 | 70 |
| Addie Joss (OTT) | 1 | 71 |
| Christy Mathewson (NOH) | 2 | 71 |
| Christy Mathewson (VGA) | 3 | 71 |
| Robin Roberts (OTT) | 2 | 71 |
| Don Sutton (NOH) | 4 | 73 |
| Mordecai Brown (NOH) | 1 | 74 |
| Walter Johnson (VGA) | 1 | 74 |